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Illustration
A slag with high value of is desirable for efficient desulphurization. Consider two different slags whose partition coefficient is 80 and 500. Amount of slag injected is , , and 12 kg/ton. To illustrate the role of transitory and permanent contact on desulphurization ,let use calculate for each case: The following table gives the calculated values
kg/ton
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trans.
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perm.
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trans..
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perm.
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4 |
0.73 |
0.14 |
0.14 |
0.33 |
8 |
0.53 |
0.018 |
0.018 |
0.20 |
12 |
0.38 |
0.0025 |
0.0025 |
0.14 |
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We note the following:
- Both amount of slag and partition coefficient are important for desulphurization
- At lower amount of slag and lower partition coefficient there is not much difference in the ratio of
for both permanent and transitory contact modes.. For example for , when the powder injection rate is 4 kg/ton, the said ratio is 0.73 for transitory and 0.76 for permanent contact. However, when the powder injection rate is increased to 8 and 12 kg/ton, transitory contact mode becomes more efficient than permanent contact.
- At higher value of
, transitory contact gives much lower value of sulphur in metal than permanent contact
Transitory contact mode requires designing powder injection systems which can inject powder at constant and uniform rate.
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