Module 3: :Ladle Metallurgy
  Lecture 23: Injection ladle metallurgy
 

Illustration

A slag with high value of  is desirable for efficient desulphurization. Consider two different slags whose partition coefficient is 80 and 500. Amount of slag injected is , , and 12 kg/ton. To illustrate the role of transitory and permanent contact on desulphurization ,let use calculate for each case: The following table gives the calculated values

                                                                                                     

  kg/ton

 trans.

 perm.

 trans..

 perm.

4

0.73

0.14

0.14

0.33

8

0.53

0.018

0.018

0.20

12

0.38

0.0025

0.0025

0.14


We note the following: 

  • Both amount of slag and partition coefficient are important for desulphurization

  • At lower  amount of slag and lower partition coefficient there is not much difference in the ratio of   for both permanent and transitory contact modes.. For example for  , when the powder injection rate is 4 kg/ton, the said ratio is 0.73 for transitory and 0.76 for permanent contact. However, when the powder injection rate is increased to 8 and 12 kg/ton, transitory contact mode becomes more efficient than permanent contact.  

  • At higher value of , transitory contact gives much lower value of sulphur in metal than permanent contact

Transitory contact mode requires designing powder injection systems which can inject powder at constant and uniform rate.