Part VI : Heat treatment
Module 1 : Hardness and hardenability: an inside view
 
1.2 Hardenability
Hardenability is the ability for a material to harden; it refers not to the highest value of hardness that can be obtained but to the capacity (depth or thickness over which such high hardness values can be achieved) to harden. Thus, hardenability is intimately related to the cooling rate that can be
achieved (especially in steels). Typically, hardenability is tested using hardness penetration diagram test (in which, the hardness of a hardened sample is plotted as a function of depth from the surface), and Jominy end quench test (in which one end of a sample is quenched and the hardness at equal intervals from the quenched end is measured and plotted).
1.2.1 Effect of alloying elements on hardenability
In steels, alloying elements are added to increase hardenability; this is achieved by delaying the time required to transform austenite into ferrite and pearlite (and thus shifting the nose of the C curve in the TTT diagram to longer times), which helps in the formation of martensites even with slower cooling rates.

The alloying elements delay the decomposition of austenite into ferrite and parlite by reducing either the nucleation or the growth. The alloying elements in steel are distinguished into two types: namely, austenite stabilizers (Mn, Ni, Cu) and ferrite stabilizers (Cr, Mo, Si). Even though both these additions help hardenability, the mechanisms involved are different.