Lecture 3 : Evolution of Engineering Materials - - Traditional Materials
Materials of Future
Bulk Metallic Glasses:
It is known that amorphous metals can be produced by rapid cooling from the liquid rate.
Until recently, the cooling rates achievable were on the order of 105-106 K/s, which
limited the thickness of a fully amorphous alloy to fractions of a millimeter. The resulting
ribbons and wires were used in transformer cores and magnetic sensors. The
recent development of bulk metallic glasses (BMG's) has opened the door for use of
these fascinating materials in structural applications. By developing certain Eutectic
mixtures the cooling rate has come down to only 1-10 K/s, hence, amorphous castings
up to a centimeter thick can be manufactured today.
For a Zr-Ti-Ni-Cu-Be bulk amorphous alloy, tensile strength of 2 GPa and fracture
toughness values of ~20 MPa m1/2 have been reported. With a density of 6.1 g/cm3, this
BMG has a higher strength to weight ratio than steels and most of the titanium
alloys. Though the alloy exhibits almost no plastic strain at failure, but typically shows up
to 2.5% elastic strains. This ability to store large amount of energy per unit
volume during elastic deformation makes the alloy an excellent candidate for making springs. In fact, it's first commercial application is as
a golf club head!
Nanocomposites:
Nanocomposites refer to a group of composites where nano-sized particles/fibres are
reinforced in polymeric or ceramic matrix to obtain extraordinarily high mechanical
properties. Structurally the reinforcements may form a three dimensional, two dimensional or one
dimensional network inside the composite. The most common of such composites are the lamellar nanocomposites
which are again divided into two categories known as intercalated and exfoliated. Extensive
researches are currently going on to understand the structure-function relationships in these nanocomposites.
However, enormous improvement in elastic modulus, strength and damping are reported
almost in all the cases.