Module 4 :
Lecture 22 : Special type of Composites - Ceramic Matrix Composite
 


Processing of CMCs

Ceramics are commonly prepared using the following technologies:

  • Sintering, Slip Casting, Chemical Vapour Deposition (CVD), Lanxide and Chemical Reaction

  • Sintering
    • The ceramic powder is mixed with binder & whiskers etc and then shaped under high pressure.
    • The temperature is elevated to improve the strength and burn off the binder.

  • Slip Casting - slurry is prepared by dissolving material in water (PH control), cast in a preform and then heat is applied with or without pressure.

  • Slurry infiltration: Nicalon fibre, Glass Matrix

  • Chemical Vapour Deposition (CVD) - Carrier Gas + Gaseous Reactant in the deposition chamber to deposit coating in fibers eg. TiCl4 + 2BCl3 + 5H2 = TiB2 + 10 HCl

  • Lanxide : Reaction of Molten metal and a Gas Al +air = Al2O3 , Al+N - AlN : Used for small parts

  • In-situ Process : In the in-situ process, both fibre and the matrix are developed simultaneously. The examples below explains the concept.

    2AlN+B2 O3 = Al2 O3 + 2BN - least expensive exothermic like:
    4Al+3TiO2 +3C=2Al2 O3 +3TiC