Module 1 :
Lecture 2 : System, Surroundings and Properties
 


Property

To describe a system and predict its behaviour requires a knowledge of its properties and how those properties are related. Properties are macroscopic characteristics of a system such as mass, volume, energy, pressure and temperature to which numerical values can be assigned at a given time without knowledge of the past history of the system. Many other properties are considered during the course of our study.

  • The value of a property of a system is independent of the process or the path followed by the system in reaching a particular state.

  • The change in the value of the property depends only on the initial and the final states.

The word state refers to the condition of a system as described by its properties.

Mathematically, if P is a property of the system, then the change in the property in going from the initial state 1 to the final state 2 is given by

 

If P = P (x, y) then,

 

where,

 

If , then dP is said to be an exact differential, and P is a point function. A thermodynamic property is a point function and not a path function. Pressure, temperature, volume or molar volume are some of the quantities which satisfy these requirements.