Different Approaches in the Study of Thermodynamics

Thermodynamics can be studied through two different approaches:

(a) Macroscopic Approach and

(b) Microscopic Approach

Macroscopic Approach

Consider a certain amount of gas in a cylindrical container. The volume (V) can be measured by measuring the diameter and the height of the cylinder. The pressure (P) of the gas can be measured by a pressure gauge. The temperature (T) of the gas can be measured using a thermometer. The state of the gas can be specified by the measured P, V and T . The values of these variables are space averaged characteristics of the properties of the gas under consideration. In classical thermodynamics, we often use this macroscopic approach. The macroscopic approach has the following features.

• The structure of the matter is not considered.
• A few variables are used to describe the state of the matter under consideration.
• The values of these variables are measurable following the available techniques of experimental physics.

Microscopic Approach

On the other hand, the gas can be considered as assemblage of a large number of particles each of which moves randomly with independent velocity. The state of each particle can be specified in terms of position coordinates ( x_i , y_i , z_i ) and the momentum components ( p_xi , p_yi , p_zi ). If we consider a gas occupying a volume of 1 cm³ at ambient temperature and pressure, the number of particles present in it is of the order of 10²⁰ . The same number of position coordinates and momentum components are needed to specify the state of the gas. The microscopic approach can be summarized as:

• A knowledge of the molecular structure of matter under consideration is essential.
• A large number of variables are needed for a complete specification of the state of the matter.