1952 |
Prof A. J. Haagen- Smit of Univ. of California demonstrated that the photochemical reactions between unburned hydrocarbons (HC) and nitrogen oxides (NOx) are responsible for smog (brown haze) observed in Los- Angeles basin |
1965 |
The first vehicle exhaust emissions standards were set in California, USA |
1968 |
The exhaust emission standards set for the first time throughout the USA |
1970 |
Vehicle emission standards set in European countries |
1974 |
Exhaust catalytic converters for oxidation of carbon monoxide (CO) and HC were needed in the US for meeting emission targets. Phasing-out of tetra ethyl lead (TEL), the antiknock additive from gasoline begins to ensure acceptable life of the catalytic converters |
1981 |
Three-way catalytic converters and closed-loop feedback air-fuel ratio control for simultaneous conversion of CO, HC and NOx introduced on production cars |
1992 |
Euro 1 emission standards needing catalytic emission control on gasoline vehicles implemented in Europe |
1994 |
Catalytic emission control for engines under lean mixture operation introduced |
1994 |
US Tier -1 standards needing reduction in CO by nearly 96%, HC by 97.5% and NOx by 90% |
2000-2005 |
Widespread use of diesel particulate filters and lean de-NOx catalyst systems on heavy duty vehicles |
2004 |
US Tier -2 standards needing reduction in CO by nearly 98 %, HC by 99% and NOx by 95% |