Module 5 : Modern Characterization of materials

Lecture 27: Characterization of Powders, Porous Solids and Suspensions

 

• For a system of particles undergoing Brownian motion, a speckle pattern is observed where the position of each speckle is seen to be in constant motion. This is because the phase addition from the moving particles is constantly evolving and forming new patterns.

• The rate at which these intensity fluctuations occur will depend on the size of the particles. Figure above schematically illustrates typical intensity fluctuations arising from a dispersion of large particles and a dispersion of small particles.

• The small particles cause the intensity to fluctuate more rapidly than the large ones.

• It is possible to directly measure the spectrum of frequencies contained in the intensity fluctuations arising from the Brownian motion of particles, but it is inefficient to do so. The best way is to use a device called a digital auto correlator .