Generic metallocene Cp2M type complexes are formed for many from across the 1st row transition metal series along Sc to Zn. The number of unpaired electrons thus correlates with the number unpaired electrons present in the valence orbital of the metal (Figure 4). Of the complexes of the 1st row transition metal series, the manganocene exists in two distinct forms, one in a high-spin form with five unpaired electrons, e.g. as in Cp2Mn and the other in a low-spin form with one unpaired electron, e.g. as in Cp*2Mn owing to the higher ligand field strength of the Cp* ligand. Cobaltocene, Cp2Co, has 19 valence electrons (VE) and thus gets easily oxidized to the diamagnetic 18 VE valence electron species, Cp2Co+. Of these metallocenes, the much-renowned ferrocene, Cp2Fe is a diamagnetic 18 VE complex, whose molecular orbital diagram is shown above (Figure 3). |