Module 8: "Stability of Colloids"
  Lecture 40: ""
 

 

Fig.10.11: Comparison of V curve vs stability ratio curve

Stability factor being given by

Let rm be the separation distance between 2 particles at which the maxima in energy occurs. It can be approximated that centre to centre distance (r) between particles is the sum of rm and radii of the 2 particles. Thus,

(10.28)

Expanding u by Taylor series about um the maximum of energy we get

(10.29)

as rm is the point where the energy is maximum. Substituting the values from equation (10.28) and (10.29) in equation (10.27) we get

(10.30)