Module 3: "Thin Film Hydrodynamics"
  Lecture 15: ""
 

Energy of Adhesion

1. (Energy of adhesion in vacuum)

(4.6)

 

 

Therefore, in vacuum is always negative.

Note: are all positive quantities. has units of energy per unit area.

If

A lesser value of would mean that is more positive. This implies that the surface would be more wettable.

2. (Energy of adhesion in the presence of an intervening fluid)

 

 

 
(4.7)