Module 3: "Components of Surface Energy"
  Lecture 14: ""
 

 

3. Mono-polar surface and monopolar liquid , i.e.

Usually only electron donor polarity is observed.

This is similar to the case where there was an apolar liquid on a surface. This is because for AB interactions to have any significance, both the conjugate interactions should be present.

Some numbers have been presented below for better understanding.

1. Monopolar surfaces ( )

          Table 4.1:

Substance

DMSO

35

41

Benzene

1.9

28.9

Toluene

1.6

28.5

Gelatin, PMMA, PVA, dextran, PEG, serum, albumin, and agarose are some other examples of important monopolar liquids.

2. Apolar and liquids having both electron donor and acceptor capabilities

Table 4.2:

Substance

Water

21.8

25.5

25.5

72.8

glycerol

34

57.4

3.92

64

Formamide

39

39.6

2.28

58

Diiodomethane

50.8

-

-

50.8

-bromonaphthalene

44.4

-

-

44.4

Note: It might appear that glycerol is monopolar with electron donor capability as is quite high for it. But it is not so, because the product  is comparable to  in magnitude.