3. Mono-polar surface and monopolar liquid , i.e.
Usually only electron donor polarity is observed.
This is similar to the case where there was an apolar liquid on a surface. This is because for AB interactions to have any significance, both the conjugate interactions should be present.
Some numbers have been presented below for better understanding.
1. Monopolar surfaces ( )
Table 4.1:
Substance |
|
|
DMSO |
35 |
41 |
Benzene |
1.9 |
28.9 |
Toluene |
1.6 |
28.5 |
Gelatin, PMMA, PVA, dextran, PEG, serum, albumin, and agarose are some other examples of important monopolar liquids.
2. Apolar and liquids having both electron donor and acceptor capabilities
Table 4.2:
Substance |
|
|
|
|
Water |
21.8 |
25.5 |
25.5 |
72.8 |
glycerol |
34 |
57.4 |
3.92 |
64 |
Formamide |
39 |
39.6 |
2.28 |
58 |
Diiodomethane |
50.8 |
- |
- |
50.8 |
-bromonaphthalene |
44.4 |
- |
- |
44.4 |
Note: It might appear that glycerol is monopolar with electron donor capability as is quite high for it. But it is not so, because the product is comparable to in magnitude.
|