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Fenimore (Prompt) Mechanism
- Prompt mechanism refers to the
which are formed very quickly by interaction of active hydrocarbon species derived from fuel with nitrogen and oxygen.
- They are generally not observed in flames of non-hydrocarbon flames.
- They cannot be formed by just heating nitrogen with oxygen.
- During initial phase of combustion, the radials with carbon atom react with
to produce N.
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--------(4) |
- This reaction is the main path which dictates the rate at which radical ‘N' is formed.
- The radical ‘N' can also be formed by the following reaction.
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--------(5) |
- When the equivalence ratio is less than 1.2, HCN can be converted to NO as follows,
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