Module 7: Combustion and Environment
  Lecture 39: Emission and Its Control
 


Fenimore (Prompt) Mechanism

  • Prompt mechanism refers to the which are formed very quickly by interaction of active hydrocarbon species derived from fuel with nitrogen and oxygen.
  • They are generally not observed in flames of non-hydrocarbon flames.
  • They cannot be formed by just heating nitrogen with oxygen.
  • During initial phase of combustion, the radials with carbon atom react with to produce N.
--------(4)
  • This reaction is the main path which dictates the rate at which radical ‘N' is formed.
  • The radical ‘N' can also be formed by the following reaction.
--------(5)
  • When the equivalence ratio is less than 1.2, HCN can be converted to NO as follows,
--------(6)
--------(8)
--------(7)
--------(9)