Module 7: Combustion and Environment
  Lecture 36: Atmosphere
 


Atmosphere (Contd..)

Troposphere

  • Region where we are living.
  • Contains 90% of the mass of the atmosphere.
  • Starts at ground level with 228 K and ends at 18 km (200 K) with 6 K drop in temperature per km altitude.
  • Beyond 18 km, temperature rises. This inflection point is called “Tropopause”.
  • Tropopause divides troposphere from stratosphere.
  • Atmospheric boundary layer - 2 km from the ground level.
  • Combustion byproducts instantly affects this region.

Photochemical chain reaction begin with dissociation of ozone as given below

--------(1)

The atomic oxygen reacts with water vapor to form hydroxyl radical

 
--------(2)

The OH radical reacts with CO and initiates other chain reactions as below

 
--------(3)
--------(4)