| |
From collision theory,
|
| |
| |
| |
|
|
| |
- Collision frequency, |
| |
- Steric factor, |
| |
- Boltaman's energy probability factor |
| |
- Activation energy |
| |
|
(Figure 19.2)
|
From kinetic theory,
|
 |
| |
- Average effective collision diameter between molecules A and B, |
| |
- Boltaman's constant = 1.381 X 10-23J/K |
| |
- Reduced mass
 |
Reaction rate
|
|
| |
|
(Pre-exponential Factor)
|
| |
|
| |
| |
| |
| |
| |
| |
| |
| |
| |
| |
| |
| |
| |
| |
|
|
|
|
