Hello, welcome everybody to the first class
of this course.
Actually, in any introductory course, everyone
is curious to know that why I should take
this course.
So, I will try to answer that question first
through some two modules that what is the
importance and the relevance of this subject
in the engineering domain.
Now, before we go to the subject we must understand
what is that we will be processing.
we’re saying that its minerals, but before
that, we should know that what is the definition
of minerals?
Now, if we look at the textbook definition
is says that minerals are natural it has to
be natural, is available in organic substances
which should possess definite chemical compositions
and atomic structures.
I repeat it the textbook definition of minerals
is that these are naturally inorganic substances
possessing definite chemical compositions
and atomic structures.
Is it really true always?
No, there are some exceptions.
Like many minerals they exhibit isomorphism
what does it mean isomorphism, this means
that were the substitution of atoms within
the crystal structure by similar atoms takes
place without affecting the atomic structure.
it may look a little bit difficult to understand,
but I am trying to explain it with an example.
Take the case of olivine.
it is a mineral.
it has got the chemical composition that is
(Mg, Fe)2SiO4 there is a chemical composition
of olivine.
but if you have olivines from 3 4 different
origins you will find that the ratio of these
Mg atoms to Fe atoms they vary in different
sources that is olivine coming from different
sources.
However, the total number of Mg and Fe atoms
in all the olivines has the same ratio to
that of that Si and oxygen atoms that is silicon
and oxygen atoms.
So, what I am trying to say that although
the olivine has that chemical composition,
the fixed chemical composition.
But the ratio of Mg atoms to Fe atoms they
varying different olivines.
And this may be the cases, but what we will
see that the total number of Mg and Fe atoms
in all olivines they have the same ratio to
that of the silicon and oxygen atoms.
So, when we get this type of properties in
any mineral we call it that this is the process
of isomorphism.
Similarly, there may be polymorphism also.
What is polymorphism?
Now, in this case, the different minerals
they may have the same chemical composition,
but their physical properties could be different
due to different crystal structure.
When I give this example you will all say
oh my goodness we all know this, like to graphite
and diamond they are exactly the same composition
being composed entirely of carbon atoms.
However, they have got widely varying different
properties.
Why?
Now, because it is of the how the carbon atoms
they are getting arranged in that crystal
lattice.
So, that dictates the property or the physical
property to be precise of that particular
mineral.
And when we see this type of characteristics
into a mineral we call it is a polymeric prism.
It is a polymorphism.
So, these are only the exceptions, but on
an average, we go by the textbook difference
say actually textbook definitions of minerals.
Now, interestingly the term mineral is often
used in a much more extended sense to include
anything of economic value which is extracted
from the earth.
So, although by definition they are not mineral,
but we group them that is their productivity,
their applications, their economics related
issues- they are all tabulated with the conventional
minerals.
Examples- a coal, chalk, clay, granite, they
all do not come under the definition of minerals
like coal.
For example, coal is not purely inorganic
it has got inorganic part, it has got organic
part.
We call it we call it minerals and macerals.
But still our mining engineers they are trained
in mining of coal also as well as the minerals.
Even the mineral processing engineers who
are busy in processing minerals they also
have good understanding about how to process
the coal.
So, what are these materials basically?
So, these materials are in fact, a rock sometimes
we call it stratified rocks which are not
homogeneous in chemical and physical composition
as the minerals do, but generally consist
of a variety of minerals and for large parts
of the earth crust.
We look at another example and it is granite.
What is it?
It is igneous rock formed by cooling of molten
material or magma and is composed of three
main mineral constituents called feldspar
quartz and mica.
These 3 homogeneous mineral components occur
in ranging proportions in different parts
of the same granite mass.
So, what will happen?
When the proportions are different the properties
the physical properties of granite they also
vary.
Look at coal, depending upon its age that
is age of formation, it is a million years
not in few years and what kind of processes
they have converted our some of the materials
into coal that dictates that what will be
the physical property of this coal.
So, relatively immature coal I say, there
is around 50 million years.
So, something like that we say they are called
peat, relatively more matured we call it lignite
or brown coal then depending on their your
because the coal formation is basically a
combination of different processes as the
geology say is a prolonged heat and pressure
for millions of years.
And when the coal becomes more mature we call
it bituminous coal then it has got some subdivision
we call it sub-bituminous and then we have
anthracite also.
So, why do you classify them?
Because their physical properties like are
different based on the geological formation
their maturities and all this.
Interestingly if you see that what constitutes
our earth crust that only 8 elements they
account for over 99 percent of the earth crust,
is it not fascinating?
Out of this 8 elements 74.6 percent is silicon
and oxygen and only three of the industrially
important metals like your aluminum, iron
and magnesium are present in amounts above
2 percent in the earth crust.
All the other useful metals they occur in
amounts below even 0.1 percent for example,
you take copper.
If the copper is evenly distributed which
is one of the most important non ferrous metals
in the earth crust its concentration is only
0.0055 percent.
So, when they are basically distributed like
this that is what the thin concentration that
is if they are distributed evenly all throughout
the earth crust it will be possibly in uneconomically
it would be impossible to extract them and
just imagine that if we cannot extract them
what would happen to the civilization.
But we are very fortunate that these geological
conditions throughout the life of the mineral
they vary and this occurrence of minerals
in nature is regulated by these geological
conditions and due to the action of many natural
agencies like your rain your say you, it is
basically the volcanic eruptions then storms,
floods and all this.
So, they carry these minerals certain minerals
and they deposit into some other place where
they are being concentrated.
So, that is how the thinly dispersed valuable
minerals the nature has already helped us
to get them concentrated at different zones
and because of that it is now possible to
extract them from the earth crust.
So, it is a responsibility of the geologists
to identify those resources that were had
they are basically concentrated, they now
are mining engineers, they plan that how to
take it out and then say for an economically
viable manner from the earth crust.
Then it is coming to the mineral processes
that is how do I upgrade the quality of that.
So, this is how this cycle goes on.
So, basically the first concentration process
has been done by the nature itself.
Now, what happens with the development of
the new discoveries and as a result of research
we could find many mineral deposits which
with the existing technologies we say that
they are basically amenable for upgradation
for the further extraction processes.
So, that we get our valuable metals out of
that.
So, and that we call it the ore.
So, when a mineral qualifies for an extraction
process and that is being dictated by for
that the economics will be in favor of that
or not.
So, then we say that mineral is a ore discuss
more on this.
So, you will look at the ores the most ores
are mixtures of extractable minerals and extraneous
rocky material described as gangue.
To qualify as an ore it is not necessary that
you have to have only that mineral only I
will give examples.
However, you have to mind some of the extraneous
rocky materials also are our strategies that
let us mined it first and then we will discard
the gangue materials, in due course of time
with economically viable manner.
So, based on the natural occurrence of this
valuable mineral we use different terminologies.
Like sometimes we say that it is a native
ore. native ore means the metal is present
in the elementary form.
elementary form means like example is gold
we call it is a native ore.
Then in some formation we say that we see
that that there are deposits where you have
gotmore than one valuable mineral available
and when we deal with that we call it as a
complex ore.
Like your copper lead zinc ore, you mine all
these ores together and then we try to separate
it out by subsequent processes.
Then many times depending on the characteristic
depending on the chemical compositions of
that ore we also apply certain terminologies
like we call it sulfide ores that is when
the metal bearing mineral is basically sulfides
like CuFeS2, we call it chalco pyrite.
So, that is a sulfide mineral.
Then when they are in oxidized form, we call
it that they are oxidized ores.
Like we have got this oxidation state maybe
in the oxide ore like Fe2O3 call it hematite,
we may have sulfate, we may have silicates,
we may have carbonates or some hydrated form
of this.
So, all this will group together into under
oxidize ores.
Why do we do it?
What I know that this is a sulphide ore.
So, automatically the strategy comes into
our mind that if this is a sulphide ore we
should do this this this, we should first
try with this this this.
However the oxide ore we should do this this
this based on our past experiences.
And we also have an idea that what kind of
waste materials we are going to handle, what
kind of environmental problems we are going
or handle, are going to face.
So, all these sorts of something like your
priori information we get when we categorize
the ores in this fashion.
Sometimes the ores are also classified by
the nature of their impurities that is the
associated gangue materials which we do not
want, but it is unavoidable we have to mine
that, as I had already explained.
So, then based on the characteristics of the
gang materials sometimes we term them as calcareous
like your calcareous phosphetic ores.
So, when I am saying calculus; that means,
we have got CaCO3 that we have got limestone
enrich mineral or the ore.
Sometimes we call it your basic that is your
lime rich and sometimes we call it siliceous
or acidic that is silica rich.
So, again the objecting is same that is when
you know that these the gangue materials are
calcareous or basic or siliceous or acidic
we have our own strategy to try for us that
how do we deal with this.
Finally, so what is that textbook definition
of an ore?
So, an ore can be described, an ore can be
described as an accumulation of mineral in
sufficient quantity as to be capable of economic
extraction.
So, when we start mining something, you must
ensure because mining is basically business
we’re to make profit out of that, if our
entire mining operation why do mine it we
are mining it to sell it who are my customers?
mostly the metallurgist.
So, what is their requirement I must know
that, and what is the value I will be getting,
what is the price I will be getting, how much
is the cost I have put in the mining and what
is the return on investment if it is positive
then only we say that this is an ore.
So that means, a mineral to qualify as an
ore has to have sufficient quantity as to
be capable of economic extraction.
So, here I have saved sufficient quantity.
So, you may ask me, sir what is the sufficient
quantity 5 percent, 10 percent, 50 percent
yeah that is a genuine question.
Now, this minimum metal contained we use one
word that is called grade or that sometimes
assay content.
So, the minimum metal content required for
a deposit to qualify as an ore it varies from
metal to metal.
What does it mean?
You will be surprised to know that gold may
be recovered profitably in ores containing
only 5 parts per million of the metal; that
means, in 1 ton of material whatever you mined
if you have 5 grams of gold that qualifies
for a very good quality gold ore.
Whereas, for iron ores containing less than
15 percent metal as of now it is regarded
as a low grade.
So, to sum up how much is the how much quantity
is the sufficient quantity?
I have rewritten it by sentence that it varies
from metal to metal.
What is the market price of that?
So, you see that in case of gold even 5 ppm
concentration in 1 ton we say that this is
a ore whereas, for iron ore even 15 percent
metal contained does not qualify to when ore.
So, what is the definition basically the mining
engineers or processing engineers they apply
or even the geologists they applied that whether
this is the mineral deposit or this is a ore.
So, it deposit will be economic to work and
can be classified as an ore deposit if the
contained value per ton is greater than total
processing cost.
it includes, geological exploration, mining,
mineral processing, even metallurgical extraction
plus in the process how much you are losing
that is the losses and other cost per ton.
So, ultimately if I make a profit out of this
then only it qualifies to be an ore.
So, in my next lecture I will explain this
in much more detailed that one of these total
processing cost losses and other cost and
what is the role of mineral processing.
Thank you very much.