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Hello, welcome everybody to the first class of this course.
Actually, in any introductory course, everyone is curious to know that why I should take
this course.
So, I will try to answer that question first through some two modules that what is the
importance and the relevance of this subject in the engineering domain.
Now, before we go to the subject we must understand what is that we will be processing.
we’re saying that its minerals, but before that, we should know that what is the definition
of minerals?
Now, if we look at the textbook definition is says that minerals are natural it has to
be natural, is available in organic substances which should possess definite chemical compositions
and atomic structures.
I repeat it the textbook definition of minerals is that these are naturally inorganic substances
possessing definite chemical compositions and atomic structures.
Is it really true always?
No, there are some exceptions.
Like many minerals they exhibit isomorphism what does it mean isomorphism, this means
that were the substitution of atoms within the crystal structure by similar atoms takes
place without affecting the atomic structure.
it may look a little bit difficult to understand, but I am trying to explain it with an example.
Take the case of olivine.
it is a mineral.
it has got the chemical composition that is (Mg, Fe)2SiO4 there is a chemical composition
of olivine.
but if you have olivines from 3 4 different origins you will find that the ratio of these
Mg atoms to Fe atoms they vary in different sources that is olivine coming from different
sources.
However, the total number of Mg and Fe atoms in all the olivines has the same ratio to
that of that Si and oxygen atoms that is silicon and oxygen atoms.
So, what I am trying to say that although the olivine has that chemical composition,
the fixed chemical composition.
But the ratio of Mg atoms to Fe atoms they varying different olivines.
And this may be the cases, but what we will see that the total number of Mg and Fe atoms
in all olivines they have the same ratio to that of the silicon and oxygen atoms.
So, when we get this type of properties in any mineral we call it that this is the process
of isomorphism.
Similarly, there may be polymorphism also.
What is polymorphism?
Now, in this case, the different minerals they may have the same chemical composition,
but their physical properties could be different due to different crystal structure.
When I give this example you will all say oh my goodness we all know this, like to graphite
and diamond they are exactly the same composition being composed entirely of carbon atoms.
However, they have got widely varying different properties.
Why?
Now, because it is of the how the carbon atoms they are getting arranged in that crystal
lattice.
So, that dictates the property or the physical property to be precise of that particular
mineral.
And when we see this type of characteristics into a mineral we call it is a polymeric prism.
It is a polymorphism.
So, these are only the exceptions, but on an average, we go by the textbook difference
say actually textbook definitions of minerals.
Now, interestingly the term mineral is often used in a much more extended sense to include
anything of economic value which is extracted from the earth.
So, although by definition they are not mineral, but we group them that is their productivity,
their applications, their economics related issues- they are all tabulated with the conventional
minerals.
Examples- a coal, chalk, clay, granite, they all do not come under the definition of minerals
like coal.
For example, coal is not purely inorganic it has got inorganic part, it has got organic
part.
We call it we call it minerals and macerals.
But still our mining engineers they are trained in mining of coal also as well as the minerals.
Even the mineral processing engineers who are busy in processing minerals they also
have good understanding about how to process the coal.
So, what are these materials basically?
So, these materials are in fact, a rock sometimes we call it stratified rocks which are not
homogeneous in chemical and physical composition as the minerals do, but generally consist
of a variety of minerals and for large parts of the earth crust.
We look at another example and it is granite.
What is it?
It is igneous rock formed by cooling of molten material or magma and is composed of three
main mineral constituents called feldspar quartz and mica.
These 3 homogeneous mineral components occur in ranging proportions in different parts
of the same granite mass.
So, what will happen?
When the proportions are different the properties the physical properties of granite they also
vary.
Look at coal, depending upon its age that is age of formation, it is a million years
not in few years and what kind of processes they have converted our some of the materials
into coal that dictates that what will be the physical property of this coal.
So, relatively immature coal I say, there is around 50 million years.
So, something like that we say they are called peat, relatively more matured we call it lignite
or brown coal then depending on their your because the coal formation is basically a
combination of different processes as the geology say is a prolonged heat and pressure
for millions of years.
And when the coal becomes more mature we call it bituminous coal then it has got some subdivision
we call it sub-bituminous and then we have anthracite also.
So, why do you classify them?
Because their physical properties like are different based on the geological formation
their maturities and all this.
Interestingly if you see that what constitutes our earth crust that only 8 elements they
account for over 99 percent of the earth crust, is it not fascinating?
Out of this 8 elements 74.6 percent is silicon and oxygen and only three of the industrially
important metals like your aluminum, iron and magnesium are present in amounts above
2 percent in the earth crust.
All the other useful metals they occur in amounts below even 0.1 percent for example,
you take copper.
If the copper is evenly distributed which is one of the most important non ferrous metals
in the earth crust its concentration is only 0.0055 percent.
So, when they are basically distributed like this that is what the thin concentration that
is if they are distributed evenly all throughout the earth crust it will be possibly in uneconomically
it would be impossible to extract them and just imagine that if we cannot extract them
what would happen to the civilization.
But we are very fortunate that these geological conditions throughout the life of the mineral
they vary and this occurrence of minerals in nature is regulated by these geological
conditions and due to the action of many natural agencies like your rain your say you, it is
basically the volcanic eruptions then storms, floods and all this.
So, they carry these minerals certain minerals and they deposit into some other place where
they are being concentrated.
So, that is how the thinly dispersed valuable minerals the nature has already helped us
to get them concentrated at different zones and because of that it is now possible to
extract them from the earth crust.
So, it is a responsibility of the geologists to identify those resources that were had
they are basically concentrated, they now are mining engineers, they plan that how to
take it out and then say for an economically viable manner from the earth crust.
Then it is coming to the mineral processes that is how do I upgrade the quality of that.
So, this is how this cycle goes on.
So, basically the first concentration process has been done by the nature itself.
Now, what happens with the development of the new discoveries and as a result of research
we could find many mineral deposits which with the existing technologies we say that
they are basically amenable for upgradation for the further extraction processes.
So, that we get our valuable metals out of that.
So, and that we call it the ore.
So, when a mineral qualifies for an extraction process and that is being dictated by for
that the economics will be in favor of that or not.
So, then we say that mineral is a ore discuss more on this.
So, you will look at the ores the most ores are mixtures of extractable minerals and extraneous
rocky material described as gangue.
To qualify as an ore it is not necessary that you have to have only that mineral only I
will give examples.
However, you have to mind some of the extraneous rocky materials also are our strategies that
let us mined it first and then we will discard the gangue materials, in due course of time
with economically viable manner.
So, based on the natural occurrence of this valuable mineral we use different terminologies.
Like sometimes we say that it is a native ore. native ore means the metal is present
in the elementary form.
elementary form means like example is gold we call it is a native ore.
Then in some formation we say that we see that that there are deposits where you have
gotmore than one valuable mineral available and when we deal with that we call it as a
complex ore.
Like your copper lead zinc ore, you mine all these ores together and then we try to separate
it out by subsequent processes.
Then many times depending on the characteristic depending on the chemical compositions of
that ore we also apply certain terminologies like we call it sulfide ores that is when
the metal bearing mineral is basically sulfides like CuFeS2, we call it chalco pyrite.
So, that is a sulfide mineral.
Then when they are in oxidized form, we call it that they are oxidized ores.
Like we have got this oxidation state maybe in the oxide ore like Fe2O3 call it hematite,
we may have sulfate, we may have silicates, we may have carbonates or some hydrated form
of this.
So, all this will group together into under oxidize ores.
Why do we do it?
What I know that this is a sulphide ore.
So, automatically the strategy comes into our mind that if this is a sulphide ore we
should do this this this, we should first try with this this this.
However the oxide ore we should do this this this based on our past experiences.
And we also have an idea that what kind of waste materials we are going to handle, what
kind of environmental problems we are going or handle, are going to face.
So, all these sorts of something like your priori information we get when we categorize
the ores in this fashion.
Sometimes the ores are also classified by the nature of their impurities that is the
associated gangue materials which we do not want, but it is unavoidable we have to mine
that, as I had already explained.
So, then based on the characteristics of the gang materials sometimes we term them as calcareous
like your calcareous phosphetic ores.
So, when I am saying calculus; that means, we have got CaCO3 that we have got limestone
enrich mineral or the ore.
Sometimes we call it your basic that is your lime rich and sometimes we call it siliceous
or acidic that is silica rich.
So, again the objecting is same that is when you know that these the gangue materials are
calcareous or basic or siliceous or acidic we have our own strategy to try for us that
how do we deal with this.
Finally, so what is that textbook definition of an ore?
So, an ore can be described, an ore can be described as an accumulation of mineral in
sufficient quantity as to be capable of economic extraction.
So, when we start mining something, you must ensure because mining is basically business
we’re to make profit out of that, if our entire mining operation why do mine it we
are mining it to sell it who are my customers?
mostly the metallurgist.
So, what is their requirement I must know that, and what is the value I will be getting,
what is the price I will be getting, how much is the cost I have put in the mining and what
is the return on investment if it is positive then only we say that this is an ore.
So that means, a mineral to qualify as an ore has to have sufficient quantity as to
be capable of economic extraction.
So, here I have saved sufficient quantity.
So, you may ask me, sir what is the sufficient quantity 5 percent, 10 percent, 50 percent
yeah that is a genuine question.
Now, this minimum metal contained we use one word that is called grade or that sometimes
assay content.
So, the minimum metal content required for a deposit to qualify as an ore it varies from
metal to metal.
What does it mean?
You will be surprised to know that gold may be recovered profitably in ores containing
only 5 parts per million of the metal; that means, in 1 ton of material whatever you mined
if you have 5 grams of gold that qualifies for a very good quality gold ore.
Whereas, for iron ores containing less than 15 percent metal as of now it is regarded
as a low grade.
So, to sum up how much is the how much quantity is the sufficient quantity?
I have rewritten it by sentence that it varies from metal to metal.
What is the market price of that?
So, you see that in case of gold even 5 ppm concentration in 1 ton we say that this is
a ore whereas, for iron ore even 15 percent metal contained does not qualify to when ore.
So, what is the definition basically the mining engineers or processing engineers they apply
or even the geologists they applied that whether this is the mineral deposit or this is a ore.
So, it deposit will be economic to work and can be classified as an ore deposit if the
contained value per ton is greater than total processing cost.
it includes, geological exploration, mining, mineral processing, even metallurgical extraction
plus in the process how much you are losing that is the losses and other cost per ton.
So, ultimately if I make a profit out of this then only it qualifies to be an ore.
So, in my next lecture I will explain this in much more detailed that one of these total
processing cost losses and other cost and what is the role of mineral processing.
Thank you very much.
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